The exact eigenfunctions and eigenvalues of a two-dimensional rigid rotor obtained using Gaussian wave packet dynamics


Exact eigenfunctions for a two‐dimensional rigid rotor are obtained using Gaussian wave packet dynamics. The wave functions are obtained by propagating, without approximation, an infinite set of Gaussian wave packets that collectively have the correct periodicity, being coherent states appropriate to this rotational problem. This result leads to a numerical method for the semiclassical calculation of rovibrational, molecular eignestates. Also, a simple, almost classical, approximation to full wave packet dynamics is shown to give exact results: this leads to an a p o s t e r i o r i justification of the De Leon–Heller spectral quantization method.

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Last updated on 10/07/2016